Desktop applications such as Outlook and Teams, will normally only prompt you to approve new logins or if you make changes to your account such as a password change.
Web-based services, such as LSE Webmail and OneFinance, will prompt you more regularly.
Please note: one indication that your account may have been compromised is that you start receiving MFA notifications when you are not trying to log in.
If you start receiving MFA notifications and you don't think you've done anything to prompt them, click "Deny", change your password and contact the Tech Support team.